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1 article(s) from Mutoh, Katsuya

Excited state dynamics for visible-light sensitization of a photochromic benzil-subsituted phenoxyl-imidazolyl radical complex

Yoichi Kobayashi,
Yukie Mamiya,
Katsuya Mutoh,
Hikaru Sotome,
Masafumi Koga,
Hiroshi Miyasaka and
Jiro Abe

Beilstein J. Org. Chem. 2019, 15, 2369–2379, doi:10.3762/bjoc.15.229

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Scheme 1: Photochromic reaction schemes of (a) PIC and (b) Benzil-PIC.

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Figure 1: Absorption spectra of PIC, benzil, and the two isomers of Benzil-PIC in benzene at 298 K. The inset...

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Figure 2: Nanosecond-to-microsecond transient absorption spectra of Benzil-PIC in benzene under (a) argon and...

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Figure 3: Femtosecond-to-nanosecond transient absorption spectra of (a) benzil and (b) Benzil-PIC (right) in ...

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Figure 4: Phosphorescence spectra of benzil at 77 K and 100 K and that of PIC at 77 K in EPA. A blue solid li...

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Figure 5: Energy diagram of the visible-light sensitized photochromic reaction of Benzil-PIC.

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Scheme 2: Synthetic procedure of Benzil-PIC (analogous to synthesis of PIC in [24]).

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Published 04 Oct 2019

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